DC Field | Value | Language |
---|---|---|
dc.contributor | Department of Applied Biology and Chemical Technology | - |
dc.creator | Tsoi, YT | - |
dc.creator | Zhou, Z | - |
dc.creator | Yu, WY | - |
dc.date.accessioned | 2015-06-23T09:11:42Z | - |
dc.date.available | 2015-06-23T09:11:42Z | - |
dc.identifier.issn | 1523-7060 | - |
dc.identifier.uri | http://hdl.handle.net/10397/30014 | - |
dc.language.iso | en | en_US |
dc.publisher | American Chemical Society | en_US |
dc.title | Rhodium-catalyzed cross-coupling reaction of arylboronates and diazoesters and tandem alkylation reaction for the synthesis of quaternary alpha,alpha-heterodiaryl carboxylic esters | en_US |
dc.type | Journal/Magazine Article | en_US |
dc.identifier.spage | 5370 | - |
dc.identifier.epage | 5373 | - |
dc.identifier.volume | 13 | - |
dc.identifier.issue | 19 | - |
dc.identifier.doi | 10.1021/ol2022577 | - |
dcterms.abstract | A rhodium-catalyzed one-pot three-component coupling reaction was developed for the synthesis of quaternary alpha,alpha-heterodiaryl carboxylic esters. This reaction involves cross-coupling of the arylrhodium(I) complexes with alpha-aryldiazoacetates to form oxa-pi-allylrhodium complexes. With KOfBu and alkyl halides, tandem alkylation of the allyl complex occurs to form a quaternary stereocenter at the carbenic carbon. | - |
dcterms.bibliographicCitation | Organic letters, 2011, v. 13, no. 19, p. 5370-5373 | - |
dcterms.isPartOf | Organic letters | - |
dcterms.issued | 2011 | - |
dc.identifier.isi | WOS:000295313900100 | - |
dc.identifier.eissn | 1523-7052 | - |
dc.identifier.rosgroupid | r61120 | - |
dc.description.ros | 2011-2012 > Academic research: refereed > Publication in refereed journal | - |
Appears in Collections: | Journal/Magazine Article |
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