DC FieldValueLanguage
dc.contributorDepartment of Applied Biology and Chemical Technology-
dc.creatorTsoi, YT-
dc.creatorZhou, Z-
dc.creatorYu, WY-
dc.date.accessioned2015-06-23T09:11:42Z-
dc.date.available2015-06-23T09:11:42Z-
dc.identifier.issn1523-7060-
dc.identifier.urihttp://hdl.handle.net/10397/30014-
dc.language.isoenen_US
dc.publisherAmerican Chemical Societyen_US
dc.titleRhodium-catalyzed cross-coupling reaction of arylboronates and diazoesters and tandem alkylation reaction for the synthesis of quaternary alpha,alpha-heterodiaryl carboxylic estersen_US
dc.typeJournal/Magazine Articleen_US
dc.identifier.spage5370-
dc.identifier.epage5373-
dc.identifier.volume13-
dc.identifier.issue19-
dc.identifier.doi10.1021/ol2022577-
dcterms.abstractA rhodium-catalyzed one-pot three-component coupling reaction was developed for the synthesis of quaternary alpha,alpha-heterodiaryl carboxylic esters. This reaction involves cross-coupling of the arylrhodium(I) complexes with alpha-aryldiazoacetates to form oxa-pi-allylrhodium complexes. With KOfBu and alkyl halides, tandem alkylation of the allyl complex occurs to form a quaternary stereocenter at the carbenic carbon.-
dcterms.bibliographicCitationOrganic letters, 2011, v. 13, no. 19, p. 5370-5373-
dcterms.isPartOfOrganic letters-
dcterms.issued2011-
dc.identifier.isiWOS:000295313900100-
dc.identifier.eissn1523-7052-
dc.identifier.rosgroupidr61120-
dc.description.ros2011-2012 > Academic research: refereed > Publication in refereed journal-
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